While
reducing red wine and olive oil in a flat frying pan on the stove, the mixture
exploded with an audible pop, spraying the wine - but not the oil - up to 2 metres
away from the pan. Significantly, the wine was not hot enough to scald me. I
hadn't stirred the pan for at least a minute, and the wine and oil had
separated. What happened?
Several
ideas about what went on here. If anyone feels the urge to find out for
themselves which scenario is correct, please exercise extreme caution
I
don't know if chefs have their own term for this phenomenon, but chemists call
it "bumping". It occurs when a liquid is heated above its boiling
point but does not boil due to a lack of nucleation sites - scratches, sharp
corners, or solid particles where bubbles form easily.
You
can observe nucleation sites in a flute of champagne. They are the spots on the
inside of the flute where bubbles are continuously forming before streaming
upwards. They usually mark the location of a tiny scratch or a speck of dust: a
very clean flute, with few or no nucleation sites, will keep your champagne
fizzy much longer.
When
there are no good nucleation sites in the frying pan, the temperature can rise
well above the liquid's normal boiling point, until it is so high that bubbles
can form even without a nucleation site. Once a bubble forms, however, it acts
as a nucleation site for the adjacent liquid. When such superheated liquid
suddenly finds itself adjacent to a nucleation site, it boils explosively. This
often happens in the chemistry lab because chemical glassware is so clean and
defect-free that it often has no nucleation sites at all.
“When
a superheated liquid is suddenly next to a nucleation site, it boils
explosively”
To
prevent bumping, a chemist might deliberately scratch the inside of a flask to
create nucleation sites, or may add chemically inert "boiling chips"
to a solution. In other cases, bumping is a necessary evil and the chemist
tries to catch or deflect the resulting spray using a "bump trap" -
usually in the form of a protective glass screen.
Nucleation
is an important concept in many disciplines. In meteorology, for example,
seeding clouds involves providing nucleation sites for the condensation of
water vapour. And in metallurgy, the way that atoms crystallise into grains
around nucleation sites greatly affects the strength and other properties of a
metal or an alloy.
In
the case mentioned above, my guess is that the wine in the frying pan bumped.
It may be that oil stuck to the surface of the pan, creating a completely
smooth surface, free of nucleation sites, or it may be that the pan was simply
very clean and smooth. The wine was presumably hot enough to scald when it left
the pan, but tiny droplets flying through the air cool rapidly. To prevent
bumping in your kitchen, you might provide some nucleation sites, perhaps by
dropping a sprig of rosemary into your oil and wine before heating it